CONCRETIONS IN PUMICEOUS TUFF.
The hill, marked in Map 2 "Crater of an old volcano," has no claims to this appellation, which I could discover, except in being surmounted by a circular, very shallow, saucer-like summit, nearly half a mile in diameter. This hollow has been nearly filled up with many successive sheets of ashes and scoriae, of different colours, and slightly consolidated. Each successive saucer-shaped layer crops out all round the margin, forming so many rings of various colours, and giving to the hill a fantastic appearance. The outer ring is broad, and of a white colour; hence it resembles a course round which horses have been exercised, and has received the name of the Devil's Riding School, by which it is most generally known. These successive layers of ashes must have fallen over the whole surrounding country, but they have all been blown away except in this one hollow, in which probably moisture accumulated, either during an extraordinary year when rain fell, or during the storms often accompanying volcanic eruptions. One of the layers of a pinkish colour, and chiefly derived from small, decomposed fragments of pumice, is remarkable, from containing numerous concretions. These are generally spherical, from half an inch to three inches in diameter; but they are occasionally cylindrical, like those of iron-pyrites in the chalk of Europe. They consist of a very tough, compact, pale-brown stone, with a smooth and even fracture. They are divided into concentric layers by thin white partitions, resembling the external superficies; six or eight of such layers are distinctly defined near the outside; but those towards the inside generally become indistinct, and blend into a homogeneous mass. I presume that these concentric layers were formed by the shrinking of the concretion, as it became compact. The interior part is generally fissured by minute cracks or septaria, which are lined, both by black, metallic, and by other white and crystalline specks, the nature of which I was unable to ascertain. Some of the larger concretions consist of a mere spherical shell, filled with slightly consolidated ashes. The concretions contain a small proportion of carbonate of lime: a fragment placed under the blowpipe decrepitates, then whitens and fuses into a blebby enamel, but does not become caustic. The surrounding ashes do not contain any carbonate of lime; hence the concretions have probably been formed, as is so often the case, by the aggregation of this substance. I have not met with any account of similar concretions; and considering their great toughness and compactness, their occurrence in a bed, which probably has been subjected only to atmospheric moisture, is remarkable.
FORMATION OF CALCAREOUS ROCKS ON THE SEA-COAST.
On several of the sea-beaches, there are immense accumulations of small, well-rounded particles of shells and corals, of white, yellowish, and pink colours, interspersed with a few volcanic particles. At the depth of a few feet, these are found cemented together into stone, of which the softer varieties are used for building; there are other varieties, both coarse and fine-grained, too hard for this purpose: and I saw one mass divided into even layers half an inch in thickness, which were so compact that when struck with a hammer they rang like flint. It is believed by the inhabitants, that the particles become united in the course of a single year. The union is effected by calcareous matter; and in the most compact varieties, each rounded particle of shell and volcanic rock can be distinctly seen to be enveloped in a husk of pellucid carbonate of lime. Extremely few perfect shells are embedded in these agglutinated masses; and I have examined even a large fragment under a microscope, without being able to discover the least vestige of striae or other marks of external form: this shows how long each particle must have been rolled about, before its turn came to be embedded and cemented. (The eggs of the turtle being buried by the parent, sometimes become enclosed in the solid rock. Mr. Lyell has given a figure ("Principles of Geology" book 3 chapter 17) of some eggs, containing the bones of young turtles, found thus entombed.) One of the most compact varieties, when placed in acid, was entirely dissolved, with the exception of some flocculent animal matter; its specific gravity was 2.63. The specific gravity of ordinary limestone varies from 2.6 to 2.75; pure Carrara marble was found by Sir H. De la Beche to be 2.7. ("Researches in Theoretical Geology" page 12.) It is remarkable that these rocks of Ascension, formed close to the surface, should be nearly as compact as marble, which has undergone the action of heat and pressure in the plutonic regions.
The great accumulation of loose calcareous particles, lying on the beach near the Settlement, commences in the month of October, moving towards the S.W., which, as I was informed by Lieutenant Evans, is caused by a change in the prevailing direction of the currents. At this period the tidal rocks, at the S.W. end of the beach, where the calcareous sand is accumulating, and round which the currents sweep, become gradually coated with a calcareous incrustation, half an inch in thickness. It is quite white, compact, with some parts slightly spathose, and is firmly attached to the rock. After a short time it gradually disappears, being either redissolved, when the water is less charged with lime, or more probably is mechanically abraded. Lieutenant Evans has observed these facts, during the six years he has resided at Ascension. The incrustation varies in thickness in different years: in 1831 it was unusually thick. When I was there in July, there was no remnant of the incrustation; but on a point of basalt, from which the quarrymen had lately removed a mass of the calcareous freestone, the incrustation was perfectly preserved. Considering the position of the tidal-rocks, and the period at which they become coated, there can be no doubt that the movement and disturbance of the vast accumulation of calcareous particles, many of them being partially agglutinated together, cause the waves of the sea to be so highly charged with carbonate of lime, that they deposit it on the first objects against which they impinge. I have been informed by Lieutenant Holland, R.N., that this incrustation is formed on many parts of the coast, on most of which, I believe, there are likewise great masses of comminuted shells.
A FRONDESCENT CALCAREOUS INCRUSTATION.
(FIGURE 5. AN INCRUSTATION OF CALCAREOUS AND ANIMAL MATTER, coating the tidal-rocks at Ascension.)
In many respects this is a singular deposit; it coats throughout the year the tidal volcanic rocks, that project from the beaches composed of broken shells. Its general appearance is well represented in Figure 5; but the fronds or discs, of which it is composed, are generally so closely crowded together as to touch. These fronds have their sinuous edges finely crenulated, and they project over their pedestals or supports; their upper surfaces are either slightly concave, or slightly convex; they are highly polished, and of a dark grey or jet black colour; their form is irregular, generally circular, and from the tenth of an inch to one inch and a half in diameter; their thickness, or amount of their projection from the rock on which they stand, varies much, about a quarter of an inch being perhaps most usual. The fronds occasionally become more and more convex, until they pass into botryoidal masses with their summits fissured; when in this state, they are glossy and of an intense black, so as to resemble some fused metallic substance. I have shown the incrustation, both in this latter and in its ordinary state to several geologists, but not one could conjecture its origin, except that perhaps it was of volcanic nature!
The substance forming the fronds has a very compact and often almost crystalline fracture; the edges being translucent, and hard enough easily to scratch calcareous spar. Under the blowpipe it immediately becomes white, and emits a strong animal odour, like that from fresh shells. It is chiefly composed of carbonate of lime; when placed in muriatic acid it froths much, leaving a residue of sulphate of lime, and of an oxide of iron, together with a black powder, which is not soluble in heated acids. This latter substance seems to be carbonaceous, and is evidently the colouring matter. The sulphate of lime is extraneous, and occurs in distinct, excessively minute, lamellar plates, studded on the surface of the fronds, and embedded between the fine layers of which they are composed; when a fragment is heated in the blowpipe, these lamellae are immediately rendered visible. The original outline of the fronds may often be traced, either to a minute particle of shell fixed in a crevice of the rock, or to several cemented together; these first become deeply corroded, by the dissolving power of the waves, into sharp ridges, and then are coated with successive layers of the glossy, grey, calcareous incrustation. The inequalities of the primary support affect the outline of every successive layer, in the same manner as may often be seen in bezoar-stones, when an object like a nail forms the centre of aggregation. The crenulated edges, however, of the frond appear to be due to the corroding power of the surf on its own deposit, alternating with fresh depositions. On some smooth basaltic rocks on the coast of St. Jago, I found an exceedingly thin layer of brown calcareous matter, which under a lens presented a miniature likeness of the crenulated and polished fronds of Ascension; in this case a basis was not afforded by any projecting extraneous particles. Although the incrustation at Ascension is persistent throughout the year; yet from the abraded appearance of some parts, and from the fresh appearance of other parts, the whole seems to undergo a round of decay and renovation, due probably to changes in the form of the shifting beach, and consequently in the action of the breakers: hence probably it is, that the incrustation never acquires a great thickness. Considering the position of the encrusted rocks in the midst of the calcareous beach, together with its composition, I think there can be no doubt that its origin is due to the dissolution and subsequent deposition of the matter composing the rounded particles of shells and corals. (The selenite, as I have remarked is extraneous, and must have been derived from the sea-water. It is an interesting circumstance thus to find the waves of the ocean, sufficiently charged with sulphate of lime, to deposit it on the rocks, against which they dash every tide. Dr. Webster has described ("Voyage of the 'Chanticleer'" volume 2 page 319) beds of gypsum and salt, as much as two feet in thickness, left by the evaporation of the spray on the rocks on the windward coast. Beautiful stalactites of selenite, resembling in form those of carbonate of lime, are formed near these beds. Amorphous masses of gypsum, also, occur in caverns in the interior of the island; and at Cross Hill (an old crater) I saw a considerable quantity of salt oozing from a pile of scoriae. In these latter cases, the salt and gypsum appear to be volcanic products.) From this source it derives its animal matter, which is evidently the colouring principle. The nature of the deposit, in its incipient stage, can often be well seen upon a fragment of white shell, when jammed between two of the fronds; it then appears exactly like the thinnest wash of a pale grey varnish. Its darkness varies a little, but the jet blackness of some of the fronds and of the botryoidal masses seems due to the translucency of the successive grey layers. There is, however, this singular circumstance, that when deposited on the under side of ledges of rock or in fissures, it appears always to be of a pale, pearly grey colour, even when of considerable thickness: hence one is led to suppose, that an abundance of light is necessary to the development of the dark colour, in the same manner as seems to be the case with the upper and exposed surfaces of the shells of living mollusca, which are always dark, compared with their under surfaces and with the parts habitually covered by the mantle of the animal. In this circumstance, – in the immediate loss of colour and in the odour emitted under the blowpipe, – in the degree of hardness and translucency of the edges, – and in the beautiful polish of the surface (From the fact described in my "Journal of Researches" of a coating of oxide of iron, deposited by a streamlet on the rocks in its bed (like a nearly similar coating at the great cataracts of the Orinoco and Nile), becoming finely polished where the surf acts, I presume that the surf in this instance, also, is the polishing agent.), rivalling when in a fresh state that of the finest Oliva, there is a striking analogy between this inorganic incrustation and the shells of living molluscous animals. (In the section descriptive of St. Paul's Rocks, I have described a glossy, pearly substance, which coats the rocks, and an allied stalactitical incrustation from Ascension, the crust of which resembles the enamel of teeth, but is hard enough to scratch plate-glass. Both these substances contain animal matter, and seem to have been derived from water in filtering through birds' dung.) This appears to me to be an interesting physiological fact. (Mr. Horner and Sir David Brewster have described "Philosophical Transactions" 1836 page 65 a singular "artificial substance, resembling shell." It is deposited in fine, transparent, highly polished, brown- coloured laminae, possessing peculiar optical properties, on the inside of a vessel, in which cloth, first prepared with glue and then with lime, is made to revolve rapidly in water. It is much softer, more transparent, and contains more animal matter, than the natural incrustation at Ascension; but we here again see the strong tendency which carbonate of lime and animal matter evince to form a solid substance allied to shell.)
SINGULAR LAMINATED BEDS ALTERNATING WITH AND PASSING INTO OBSIDIAN.
These beds occur within the trachytic district, at the western base of Green Mountain, under which they dip at a high inclination. They are only partially exposed, being covered up by modern ejections; from this cause, I was unable to trace their junction with the trachyte, or to discover whether they had flowed as a stream of lava, or had been injected amidst the overlying strata. There are three principal beds of obsidian, of which the thickest forms the base of the section. The alternating stony layers appear to me eminently curious, and shall be first described, and afterwards their passage into the obsidian. They have an extremely diversified appearance; five principal varieties may be noticed, but these insensibly blend into each other by endless gradations.
FIRST.
A pale grey, irregularly and coarsely laminated (This term is open to some misinterpretation, as it may be applied both to rocks divided into laminae of exactly the same composition, and to layers firmly attached to each other, with no fissile tendency, but composed of different minerals, or of different shades of colour. The term "laminated," in this chapter, is applied in these latter senses; where a homogeneous rock splits, as in the former sense, in a given direction, like clay-slate, I have used the term "fissile."), harsh-feeling rock, resembling clay-slate which has been in contact with a trap-dike, and with a fracture of about the same degree of crystalline structure. This rock, as well as the following varieties, easily fuses into a pale glass. The greater part is honeycombed with irregular, angular, cavities, so that the whole has a curious appearance, and some fragments resemble in a remarkable manner silicified logs of decayed wood. This variety, especially where more compact, is often marked with thin whitish streaks, which are either straight or wrap round, one behind the other, the elongated carious hollows.
SECONDLY.
A bluish grey or pale brown, compact, heavy, homogeneous stone, with an angular, uneven, earthy fracture; viewed, however, under a lens of high power, the fracture is seen to be distinctly crystalline, and even separate minerals can be distinguished.
THIRDLY.
A stone of the same kind with the last, but streaked with numerous, parallel, slightly tortuous, white lines of the thickness of hairs. These white lines are more crystalline than the parts between them; and the stone splits along them: they frequently expand into exceedingly thin cavities, which are often only just perceptible with a lens. The matter forming the white lines becomes better crystallised in these cavities, and Professor Miller was fortunate enough, after several trials, to ascertain that the white crystals, which are the largest, were of quartz (Professor Miller informs me that the crystals which he measured had the faces P, z, m of the figure (147) given by Haidinger in his Translation of Mohs; and he adds, that it is remarkable, that none of them had the slightest trace of faces r of the regular six-sided prism.), and that the minute green transparent needles were augite, or, as they would more generally be called, diopside: besides these crystals, there are some minute, dark specks without a trace of crystalline, and some fine, white, granular, crystalline matter which is probably feldspar. Minute fragments of this rock are easily fusible.
FOURTHLY.
A compact crystalline rock, banded in straight lines with innumerable layers of white and grey shades of colour, varying in width from the thirtieth to the two-hundredth of an inch; these layers seem to be composed chiefly of feldspar, and they contain numerous perfect crystals of glassy feldspar, which are placed lengthways; they are also thickly studded with microscopically minute, amorphous, black specks, which are placed in rows, either standing separately, or more frequently united, two or three or several together, into black lines, thinner than a hair. When a small fragment is heated in the blowpipe, the black specks are easily fused into black brilliant beads, which become magnetic, – characters that apply to no common mineral except hornblende or augite. With the black specks there are mingled some others of a red colour, which are magnetic before being heated, and no doubt are oxide of iron. Round two little cavities, in a specimen of this variety, I found the black specks aggregated into minute crystals, appearing like those of augite or hornblende, but too dull and small to be measured by the goniometer; in the specimen, also, I could distinguish amidst the crystalline feldspar, grains, which had the aspect of quartz. By trying with a parallel ruler, I found that the thin grey layers and the black hair-like lines were absolutely straight and parallel to each other. It is impossible to trace the gradation from the homogeneous grey rocks to these striped varieties, or indeed the character of the different layers in the same specimen, without feeling convinced that the more or less perfect whiteness of the crystalline feldspathic matter depends on the more or less perfect aggregation of diffused matter, into the black and red specks of hornblende and oxide of iron.
FIFTHLY.
A compact heavy rock, not laminated, with an irregular, angular, highly crystalline, fracture; it abounds with distinct crystals of glassy feldspar, and the crystalline feldspathic base is mottled with a black mineral, which on the weathered surface is seen to be aggregated into small crystals, some perfect, but the greater number imperfect. I showed this specimen to an experienced geologist, and asked him what it was; he answered, as I think every one else would have done, that it was a primitive greenstone. The weathered surface, also, of the banded variety in Figure 4, strikingly resembles a worn fragment of finely laminated gneiss.
These five varieties, with many intermediate ones, pass and repass into each other. As the compact varieties are quite subordinate to the others, the whole may be considered as laminated or striped. The laminae, to sum up their characteristics, are either quite straight, or slightly tortuous, or convoluted; they are all parallel to each other, and to the intercalating strata of obsidian; they are generally of extreme thinness; they consist either of an apparently homogeneous, compact rock, striped with different shades of grey and brown colours, or of crystalline feldspathic layers in a more or less perfect state of purity, and of different thicknesses, with distinct crystals of glassy feldspar placed lengthways, or of very thin layers chiefly composed of minute crystals of quartz and augite, or composed of black and red specks of an augitic mineral and of an oxide of iron, either not crystallised or imperfectly so. After having fully described the obsidian, I shall return to the subject of the lamination of rocks of the trachytic series.
The passage of the foregoing beds into the strata of glassy obsidian is effected in several ways: first, angulo-modular masses of obsidian, both large and small, abruptly appear disseminated in a slaty, or in an amorphous, pale-coloured, feldspathic rock, with a somewhat pearly fracture. Secondly, small irregular nodules of the obsidian, either standing separately, or united into thin layers, seldom more than the tenth of an inch in thickness, alternate repeatedly with very thin layers of a feldspathic rock, which is striped with the finest parallel zones of colour, like an agate, and which sometimes passes into the nature of pitchstone; the interstices between the nodules of obsidian are generally filled by soft white matter, resembling pumiceous ashes. Thirdly, the whole substance of the bounding rock suddenly passes into an angulo-concretionary mass of obsidian. Such masses (as well as the small nodules) of obsidian are of a pale green colour, and are generally streaked with different shades of colour, parallel to the laminae of the surrounding rock; they likewise generally contain minute white sphaerulites, of which half is sometimes embedded in a zone of one shade of colour, and half in a zone of another shade. The obsidian assumes its jet black colour and perfectly conchoidal fracture, only when in large masses; but even in these, on careful examination and on holding the specimens in different lights, I could generally distinguish parallel streaks of different shades of darkness.
(FIGURE 6. OPAQUE BROWN SPHAERULITES, drawn on an enlarged scale. The upper ones are externally marked with parallel ridges. The internal radiating structure of the lower ones, is much too plainly represented.
FIGURE 7. A LAYER FORMED BY THE UNION OF MINUTE BROWN SPHAERULITES, INTERSECTING TWO OTHER SIMILAR LAYERS: the whole represented of nearly the natural size.)
One of the commonest transitional rocks deserves in several respects a further description. It is of a very complicated nature, and consists of numerous thin, slightly tortuous layers of a pale-coloured feldspathic stone, often passing into an imperfect pitchstone, alternating with layers formed of numberless little globules of two varieties of obsidian, and of two kinds of sphaerulites, embedded in a soft or in a hard pearly base. The sphaerulites are either white and translucent, or dark brown and opaque; the former are quite spherical, of small size, and distinctly radiated from their centre. The dark brown sphaerulites are less perfectly round, and vary in diameter from the twentieth to the thirtieth of an inch; when broken they exhibit towards their centres, which are whitish, an obscure radiating structure; two of them when united sometimes have only one central point of radiation; there is occasionally a trace of or a hollow crevice in their centres. They stand either separately, or are united two or three or many together into irregular groups, or more commonly into layers, parallel to the stratification of the mass. This union in many cases is so perfect, that the two sides of the layer thus formed, are quite even; and these layers, as they become less brown and opaque, cannot be distinguished from the alternating layers of the pale-coloured feldspathic stone. The sphaerulites, when not united, are generally compressed in the plane of the lamination of the mass; and in this same plane, they are often marked internally, by zones of different shades of colour, and externally by small ridges and furrows. In the upper part of Figure 6, the sphaerulites with the parallel ridges and furrows are represented on an enlarged scale, but they are not well executed; and in the lower part, their usual manner of grouping is shown. In another specimen, a thin layer formed of the brown sphaerulites closely united together, intersects, as represented in Figure 7, a layer of similar composition; and after running for a short space in a slightly curved line, again intersects it, and likewise a second layer lying a little way beneath that first intersected. The small nodules also of obsidian are sometimes externally marked with ridges and furrows, parallel to the lamination of the mass, but always less plainly than the sphaerulites. These obsidian nodules are generally angular, with their edges blunted: they are often impressed with the form of the adjoining sphaerulites, than which they are always larger; the separate nodules seldom appear to have drawn each other out by exerting a mutually attractive force. Had I not found in some cases, a distinct centre of attraction in these nodules of obsidian, I should have been led to have considered them as residuary matter, left during the formation of the pearlstone, in which they are embedded, and of the sphaerulitic globules.
The sphaerulites and the little nodules of obsidian in these rocks so closely resemble, in general form and structure, concretions in sedimentary deposits, that one is at once tempted to attribute to them an analogous origin. They resemble ordinary concretions in the following respects: in their external form, – in the union of two or three, or of several, into an irregular mass, or into an even-sided layer, – in the occasional intersection of one such layer by another, as in the case of chalk-flints, – in the presence of two or three kinds of nodules, often close together, in the same basis, – in their fibrous, radiating structure, with occasional hollows in their centres, – in the co-existence of a laminary, concretionary, and radiating structure, as is so well developed in the concretions of magnesian limestone, described by Professor Sedgwick. ("Geological Transactions" volume 3 part 1 page 37.) Concretions in sedimentary deposits, it is known, are due to the separation from the surrounding mass of the whole or part of some mineral substance, and its aggregation round certain points of attraction. Guided by this fact, I have endeavoured to discover whether obsidian and the sphaerulites (to which may be added marekanite and pearlstone, both of them occurring in nodular concretions in the trachytic series) differ in their constituent parts, from the minerals generally composing trachytic rocks. It appears from three analyses, that obsidian contains on an average 76 per cent of silica; from one analysis, that sphaerulites contain 79.12; from two, that marekanite contains 79.25; and from two other analyses, that pearlstone contains 75.62 of silica. (The foregoing analyses are taken from Beudant "Traite de Mineralogie" tome 2 page 113; and one analysis of obsidian from Phillips "Mineralogy.") Now, the constituent parts of trachyte, as far as they can be distinguished consist of feldspar, containing 65.21 of silica; or of albite, containing 69.09; of hornblende, containing 55.27 (These analyses are taken from Von Kobell "Grundzuge der Mineralogie" 1838.), and of oxide of iron: so that the foregoing glassy concretionary substances all contain a larger proportion of silica than that occurring in ordinary feldspathic or trachytic rocks. D'Aubuisson ("Traite de Geogn." tome 2 page 535.), also, has remarked on the large proportion of silica compared with alumina, in six analyses of obsidian and pearlstone given in Brongniart's "Mineralogy." Hence I conclude, that the foregoing concretions have been formed by a process of aggregation, strictly analogous to that which takes place in aqueous deposits, acting chiefly on the silica, but likewise on some of the other elements of the surrounding mass, and thus producing the different concretionary varieties. From the well-known effects of rapid cooling (This is seen in the manufacture of common glass, and in Gregory Watts's experiments on molten trap; also on the natural surfaces of lava- streams, and on the side-walls of dikes.) in giving glassiness of texture, it is probably necessary that the entire mass, in cases like that of Ascension, should have cooled at a certain rate; but considering the repeated and complicated alterations of nodules and thin layers of a glassy texture with other layers quite stony or crystalline, all within the space of a few feet or even inches, it is hardly possible that they could have cooled at different rates, and thus have acquired their different textures.
The natural sphaerulites in these rocks very closely resemble those produced in glass, when slowly cooled. (I do not know whether it is generally known, that bodies having exactly the same appearance as sphaerulites, sometimes occur in agates. Mr. Robert Brown showed me in an agate, formed within a cavity in a piece of silicified wood, some little specks, which were only just visible to the naked eye: these specks, when placed by him under a lens of high power, presented a beautiful appearance: they were perfectly circular, and consisted of the finest fibres of a brown colour, radiating with great exactness from a common centre. These little radiating stars are occasionally intersected, and portions are quite cut off by the fine, ribbon-like zones of colour in the agate. In the obsidian of Ascension, the halves of a sphaerulite often lie in different zones of colour, but they are not cut off by them, as in the agate.) In some fine specimens of partially devitrified glass, in the possession of Mr. Stokes, the sphaerulites are united into straight layers with even sides, parallel to each other, and to one of the outer surfaces, exactly as in the obsidian. These layers sometimes interbranch and form loops; but I did not see any case of actual intersection. They form the passage from the perfectly glassy portions, to those nearly homogeneous and stony, with only an obscure concretionary structure. In the same specimen, also, sphaerulites differing slightly in colour and in structure, occur embedded close together. Considering these facts, it is some confirmation of the view above given of the concretionary origin of the obsidian and natural sphaerulites, to find that M. Dartigues ("Journal de Physique" tome 59 1804 pages 10, 12.), in his curious paper on this subject, attributes the production of sphaerulites in glass, to the different ingredients obeying their own laws of attraction and becoming aggregated. He is led to believe that this takes place, from the difficulty in remelting sphaerulitic glass, without the whole be first thoroughly pounded and mixed together; and likewise from the fact, that the change takes place most readily in glass composed of many ingredients. In confirmation of M. Dartigues' view, I may remark, that M. Fleuriau de Bellevue (Idem tome 60 1805 page 418.) found that the sphaerulitic portions of devitrified glass were acted on both by nitric acid and under the blowpipe, in a different manner from the compact paste in which they were embedded.